If you upgrade to EXchange 2010 SP1, then you will have the ability to alter permissions on Public Folders through the GUI, hooray.
In the meantime, the Powershell way is as follows;
Adding an Admin userAdd-PublicFolderAdministrativePermission -Identity "\
public folder name" -User "
User Name" -AccessRights AllExtendedRights -InheritanceType SelfAndChildren
See
http://technet.microsoft.com/en-us/library/aa997986.aspx for more detailed syntax
Adding a client to a public folderAdd-PublicFolderClientPermission -Identity "\
public folder name" -AccessRights
Role Type -User
User NameRole Type:
None
Owner
Editor
Author
PublishingEditor
PublishingAuthor
NonEditingAuthor
Contributor
See
http://technet.microsoft.com/en-us/library/bb124743.aspx for more detailed syntax